12th Class Chemistry Chemical Kinetics / रासायनिक बलगतिकी

  • question_answer 36)
    The rate constant for the first order decomposition of H2O2 is given by the following equation : log k = 14.34 - 1.25 x 104 K/T. Calculate the Ea for the reaction. At what temperature will the half life period be 256 minutes?  

    Answer:

    Step I. Calculation of activation energy (Ea) According to Arrhenius equation k = Ae?E a /RT log k = log The given eqn. is . On comparison: Ea = 1.25 x 104 x 2.303 x 8.314 (J mol?1) = 239,339 J mol?1 = 239.339 kJ mol?1. Step II. Calculation of desired temperature For first order reaction; = 4.51 × 10?5 s?1 According to Arrhenius theory. log k = 14.34 ?


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