12th Class Chemistry Electrochemistry / विद्युत् रसायन

  • question_answer 22)
    Define conductivity and molar conductivity for the solution of an electrolyte. Discuss their variation with concentration.  

    Answer:

    Conductivity is the conductance of the solution of an electrolyte enclosed in a cell with two electrodes of unit area of cross-section separated by one cm or it is the conductance of one centimetre cube of the solution of an electrolyte. Units. Ohm?1 cm-1 or ?1 cm?1 or S cm?1 Molar conductivity. It is defined as the conductance of all the ions produced by one gram mole of the electrolyte in solution and is denoted by . Here C is the molar concentration of the solution. Units. Ohm?1 cm2 mol?1 or S cm2 mol?1. Variation with concentration Conductivity of a solution of an electrolyte decreases with decrease in concentration. This is because conductivity depends upon number of ions per unit volume of the solution and with decrease in concentration, no. of ions per unit volume becomes lesser. Molar conductivity of a solution of an electrolyte increases with dilution. This is because with decrease in concentration, no. of ions as well as their mobility increase.


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