11th Class Chemistry Organic Chemistry: Some Basic Principles & Techniques / कार्बनिक रसायन : कुछ मूलभूत सिद्धांत एवं तकन

  • question_answer 32)
                      In the extraction of chlorine by electrolysis of brine............ (a) oxidation of  ion to chlorine gas occurs (b) reduction of  ion to chlorine gas occurs (C) for overall reaction  has negative value (D) a displacement reaction takes place

    Answer:

                                    (a) Following reaction takes place in the extraction of chlorine by electrolysis From the above reaction it is very clear that the oxidation of  ion to chlorine gas occurs Thus, option (a) is the correct answer.  for this reaction is +422KJ. Therefore, thermodynamically reaction i3 not feasible, We know that                               By using this equation value of £° can be calculated. Thus,   Therefore for the occurrence of this reaction, external potential (emf) greater than 2.2V is required. Due to this fact (c) is not the correct option.


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