12th Class Chemistry Haloalkanes and Haloarenes / हैलोएल्केन तथा हैलोएरीन्स

  • question_answer 28)
    How the following conversions can be carried out? (i) Propene to propan-1-ol (ii) Ethanol to but-1-yne (iii) 1-bromopropane to 2-bromopropane (iv) Toluene to benzyl alcohol (v) Benzene to 4-bromonitrobenzene (vi) Benzyl alcohol to 2-phenyl ethanoic acid (vii) Ethanol to propane nitrile (viii) Aniline to chlorobenzene (ix) 2-chlorobutane to 3, 4-dimethylhexane (x) 2-methyl-1-propene to 2-chloro-2-methylpropane (xi) Ethyl chloride to propanoic acid (xii) But-1-eiie to n-butyliodide (xiii) 2-chloropropane to 1-propanol (xiv) Iso-propyl alcohol to iodoform (xv) Chlorobenzene to p-nitrophenol (xvi) 2-bromopropane to 1-bromopropane (xvii) Chloroethane to butane (xviii) Benzene to diphenyl (xix) tert-butyl bromide to iso-butyl bromide (xx) Aniline to phenyl isocyanide   (i) Addition of HBr (peroxide effect); Replacement of ?Br by ?OH. (ii) ? OH is substitudedby; then substitution by alkynyl group to form higher alkyne. (iii) Dehydrohalogenation by alc. KOH (-elimination), Addition of HBr (Markownikoff rule) (iv) Chlorination of  group; Replacement  by ? OH. (v) Bromination of benzene; Nitration of bromobenzene at p-position. (vi) Replacement of ? OH by ; then  by ?CN and at last by ? COOH group. (vii) Replacement of ?OH by?l and then ?l by ?CN. (viii) Diazotization; Formation of chlrobenzene. (ix)  Preparation of alkane with double number of C-atoms (Wurtz reaction) (x) Addition of  across the double bond (Markownikoff rule) (xi) Substitution of  by ?CN; Acidic hydrolysis. (xii)  Addition of  (peroxide effect or Anti-Markownikoff?s rule); Substitution of ?Br by ?l. (xiii) Dehydrohalogenation (elimination); Addition of  (peroxide effect); Substituting of -Br by -OH by aqueous KOH. (xiv) Oxidation of alcohol to ketone, Iodoform reaction. (xv) Nitration replacement of  by ?OH;  (xvi) Dehydrohalogenation (-elimination); Addition of  (peroxide effect) (xvii) Wurtz reaction-Formation of hydrocarbon with double number of carbon atoms. (xix) Dehydrohalogenation; Addition of  (peroxide effect) (xx) Carbylamine reaction

    Answer:

    (i) (ii) (iii) (iv) (v)     (vi) (vii) (viii) (ix)   (x) (xi) (xii) (xiii) (xiv)               (xv) (xvi)
      (xvii) (xviii) For answer, consult answer of Q. 11 (part x) (xix)    


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