12th Class Chemistry The d-and f-Block Elements / d तथा f ब्लॉक के तत्व

  • question_answer 115)
        On the basis of lanthanoid contraction, explain the following: (i) Nature of bonding in  and . (ii) Trends in the stability of oxo salts of lanthanoids from La to Lu. (iii) Stability of the complexes of lanthanoids. (iv) Radii of 4cf and 5d block elements. (v) Trends in acidic character of lanthanoid oxides.

    Answer:

                        (i) As the size decreases covalent character increases. Therefore,  is more ionic and  is more covalent. (ii) As the size decreases from La to Lu, stability of oxo salts also decreases. (iii) Stability of complexes increases as the size of lanthanoids decreases. (iv) Radii of 4d and 5d - block elements will be almost same. (v) Acidic character of oxides increases from La to Lu.


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