12th Class Chemistry The p-block Elements-II / p-ब्लॉक तत्व-II

  • question_answer 7)
      Bond angle in PH4+ is higher than in PH3. Why?

    Answer:

    P in both PH3 and PH4+ is hybridized. Due to the absence of lone pair-bond pair repulsion and presence of four identical bond pair-bond pair interactions, PH4+ assumes tetrahedral geometry with a bond angle to 109° 28'. But PH3 has three bond pairs and one lone pair around P. Due to greater lone pair-bond pair repulsion than bond pair-bond pair repulsion, the tetrahedral angle decreases from 109° 28' to 93.6°. As a result, PH3 is pyramidal.


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