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question_answer1) Directions : (1-15) A statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices. Assertion: The number of tetrahedral voids is double the number of octahedral voids. Reason: The size of the tetrahedral voids is half of that of the octahedral void.
question_answer2) Assertion: The packing efficiency is maximum for fcc structure. Reason: The coordination number is 8 in fcc structure.
question_answer3) Assertion: Crystalline solids are anisotropic. Reason: Crystalline solids are not as closely packed as amorphous solids.
question_answer4) Assertion: The total number of atoms present in simple cubic unit cell in one. Reason: Simple cubic unit cell has atoms at its corners, each of which is shared between four adjacent unit cells.
question_answer5) Assertion: Certain compounds have both Schottky and Frenkel defects. Reason: Both Schottky and Frenkel defects change the density of the solids.
question_answer6) Assertion: FeO is non-stoichiometric with \[F{{e}_{0.950}}O.\] Reason: Some \[F{{e}^{2+}}\] ions are replaced by \[F{{e}^{3+}}\] as \[3F{{e}^{2+}}=2F{{e}^{3+}}\] to maintain electrical neutrality.
question_answer7) Assertion: In NaCl crystal, each \[N{{a}^{+}}\] ion is touching six \[C{{l}^{-}}\] ions but these \[C{{l}^{-}}\] ions do not touch each other. Reason: The radius ratio \[{{r}_{N{{a}^{+}}}}/{{r}_{C{{l}^{-}}}}\] is greater than 0.414 required for exact fitting.
question_answer8) Assertion: Ionic solids are made up of cations and anions. Reason: Ionic solids conduct electricity in solid state.
question_answer9) Assertion: In any ionic solid with Schottky defect, the number of positive and negative ions is same. Reason: Equal number of cationic and anionic vacancies are present.
question_answer10) Assertion: Network solids are also called giant molecules. Reason: Graphite is soft in nature and conducts electricity.
question_answer11) Assertion: In close packing of spheres, a tetrahedral void is surrounded by four spheres whereas an octahedral void is surrounded by six spheres. Reason: A tetrahedral void has a tetrahedral shape whereas an octahedral void has an octahedral shape.
question_answer12) Assertion: Anionic vacancies in alkali halides are produced by heating the alkali halide crystals with alkali metal vapour. Reason: Electrons trapped in anionic vacancies are referred to as F-centres.
question_answer13) Assertion: In ZnO, the excess \[Z{{n}^{2+}}\]ions are present in interstitial sites. Reason: Metal excess crystals have either missing cation or anion in interstitial site.
question_answer14) Assertion: bee and hcp has same packing efficiency. Reason: bcc arrangement has 2 atoms per unit cell while fcc has 4 atoms per unit cell.
question_answer15) Assertion: In CsCl crystal, \[C{{s}^{+}}\] ions adopt bcc arrangement. Reason: For N atoms adopting bcc arrangement, there are 2N tetrahedral voids.
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