JEE Main & Advanced Chemistry Coordination Chemistry Question Bank Complexes and complex stability

  • question_answer
    \[CuS{{O}_{4}}\] reacts with KCN solution and forms: [DPMT 2004]

    A) \[{{K}_{3}}[Cu{{(CN)}_{4}}]\]

    B) \[Cu(CN)\]

    C) \[Cu{{(CN)}_{2}}\]

    D) \[{{K}_{4}}[Cu{{(CN)}_{6}}]\]

    Correct Answer: A

    Solution :

      \[CuS{{O}_{4}}\] on reaction with \[KCN\] gives \[{{K}_{3}}[Cu{{(CN)}_{4}}]\] \[2CuS{{O}_{4}}+10KCN\to 2{{K}_{3}}[Cu{{(CN)}_{4}}]+2{{K}_{2}}S{{O}_{4}}+{{(CN)}_{2}}\]


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