JEE Main & Advanced Chemistry The d-and f-Block Elements / d तथा f ब्लॉक के तत्व Question Bank Compounds of Transitional Elements

  • question_answer
    Which of the following has diamagnetic character [Pb. CET 2003]

    A) \[{{[NiC{{l}_{4}}]}^{2-}}\]

    B) \[{{[Co{{F}_{6}}]}^{3-}}\]

    C) \[{{[Fe{{({{H}_{2}}O)}_{6}}]}^{2+}}\]

    D) \[{{[Ni{{(CN)}_{4}}]}^{2-}}\]

    Correct Answer: D

    Solution :

    Ni in presence of \[C{{N}^{-}}\] \[[N{{i}^{2+}}\]in presence of \[C{{N}^{-}}=[Ar]\] As \[{{[Ni{{(CN)}_{4}}]}^{2-}}\] has no unpaired electron. It is diamagnetic.


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