JEE Main & Advanced Chemistry The d-and f-Block Elements / d तथा f ब्लॉक के तत्व Question Bank Compounds of Transitional Elements

  • question_answer
    When conc. sulphuric acid is added slowly to a solution of ferrous sulphate containing nitrate ion, a brown colour ring is formed. The composition of the ring is [CPMT 1989]

    A) \[[Fe{{({{H}_{2}}O)}_{5}}NO]S{{O}_{4}}\]

    B) \[FeS{{O}_{4}}.N{{O}_{2}}\]

    C) \[Fe[{{({{H}_{2}}O)}_{5}}]{{(N{{O}_{3}})}_{2}}\]

    D) None of these

    Correct Answer: A

    Solution :

    \[NO_{3}^{-}+{{H}_{2}}S{{O}_{4}}\to HN{{O}_{3}}+HSO_{4}^{-}\] \[2HN{{O}_{3}}\to {{H}_{2}}O+2NO+3[O]\] \[FeS{{O}_{4}}+NO+5{{H}_{2}}O\to \underset{\text{Brown colour}}{\mathop{[Fe{{({{H}_{2}}O)}_{5}}N{{O}^{+}}]\,S{{O}_{4}}}}\,\]


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