JEE Main & Advanced Chemistry The d-and f-Block Elements / d तथा f ब्लॉक के तत्व Question Bank Compounds of Transitional Elements

  • question_answer
    The reaction of \[{{K}_{2}}C{{r}_{2}}{{O}_{7}}\] with \[NaCl\] and conc. \[{{H}_{2}}S{{O}_{4}}\] gives [MP PET 1994]

    A) \[CrC{{l}_{3}}\]

    B) \[CrOC{{l}_{2}}\]

    C) \[Cr{{O}_{2}}C{{l}_{2}}\]

    D) \[C{{r}_{2}}{{O}_{3}}\]

    Correct Answer: C

    Solution :

    \[NaCl+{{H}_{2}}S{{O}_{4}}+{{K}_{2}}C{{r}_{2}}{{O}_{7}}\,\to \]\[\underset{\text{Chromyl chloride}}{\mathop{Cr{{O}_{2}}C{{l}_{2}}+}}\,{{K}_{2}}S{{O}_{4}}+N{{a}_{2}}S{{O}_{4}}\]


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