JEE Main & Advanced Chemistry The d-and f-Block Elements / d तथा f ब्लॉक के तत्व Question Bank Compounds of Transitional Elements

  • question_answer
    In solid \[CuS{{O}_{4}}.5{{H}_{2}}O\] copper is co-ordinated to [MP PET 1985, 86]

    A) Five water molecules

    B) Four water molecules

    C) One sulphate anion

    D) One water molecule

    Correct Answer: B

    Solution :

    Four water molecules. \[CuS{{O}_{4}}.5{{H}_{2}}O\] is a crystalline salt. Four \[{{H}_{2}}O\] molecules attach to copper forming a square planar symmetry and two oxygen atoms from \[SO_{4}^{2-}\] ion complete the distorted octahedron. The fifth water molecule is attached through hydrogen bonding between one of the co-ordinated water molecule and one of the sulphate ion.


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