JEE Main & Advanced Chemistry Aldehydes, Ketones Question Bank Critical Thinking Aldehydes,

  • question_answer
    The most reactive compound towards formation of cyanohydrin on treatment with KCN followed by acidification is                                        [GATE 2001]

    A)                 Benzaldehyde  

    B)                 p-Nitrobenzaldehyde

    C)                 Phenyl acetaldehyde    

    D)                 p-Hydroxybenzaldehyde

    Correct Answer: B

    Solution :

                    Due to electron withdrawing nature of \[N{{O}_{2}}\] group, the partial +ve charge on the carbon atom of the \[>C=O\] group in p-nitrobenzaldehyde increases and hence becomes more susceptible to nucleophilic attack by \[C{{N}^{-}}\]ion.


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