JEE Main & Advanced Chemistry Analytical Chemistry Question Bank Critical Thinking Analytical

  • question_answer
    A salt on treatment with dil. \[HCl\] gives a pungent smelling gas and a yellow precipitate. The salt gives green flame when tested. The salt solution gives a yellow precipitate with potassium chromate. The salt is [MP PET 1996]

    A) \[NiS{{O}_{4}}\]

    B) \[Ba{{S}_{2}}{{O}_{3}}\]

    C) \[Pb{{S}_{2}}{{O}_{3}}\]

    D) \[CuS{{O}_{4}}\]

    Correct Answer: B

    Solution :

    \[B{{a}^{+2}}+2C{{H}_{3}}CO{{O}^{-}}\to {{(C{{H}_{3}}COO)}_{2}}Ba\] \[Ba{{S}_{2}}{{O}_{3}}\]gives \[S{{O}_{2}}\]gas with dil.\[HCl\]and also yellow ppt. of Barium chromate. \[(C{{H}_{3}}COO)Ba+{{K}_{2}}Cr{{O}_{4}}\to 2C{{H}_{3}}COOK+\]\[\underset{\text{(yellow ppt}\text{.)}}{\mathop{BaCr{{O}_{4}}\downarrow }}\,\]


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