JEE Main & Advanced Chemistry The d-and f-Block Elements / d तथा f ब्लॉक के तत्व Question Bank General Characteristics

  • question_answer
    Electronic configuration of \[Cu(Z=29)\] is [Pb. CET 2001]

    A) \[[Ar]3{{d}^{9}}4{{s}^{2}}\]

    B) \[[Ar]3{{d}^{10}}4{{s}^{1}}\]

    C) \[[Ar]3{{d}^{5}}4{{s}^{2}}\]

    D) \[[Ar]3{{d}^{6}}4{{s}^{2}}\]

    Correct Answer: B

    Solution :

    The expected electronic configuration of Cu (29) is \[[Ar]\ 3{{d}^{9}}4{{s}^{2}}\] but actually it is found to be \[[Ar]\ 3{{d}^{10}}4{{s}^{1}}\]. This is because fully filled d orbitals are more stable than incompletely filled d-orbitals. So there is a migration of one \[{{e}^{-}}\], from 4s orbital to 3d orbital to give a more stable configuration.


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