JEE Main & Advanced Chemistry Redox Reactions / रेडॉक्स अभिक्रियाएँ Question Bank Oxidation number and Oxidation state

  • question_answer
    The oxidation number of  S in \[{{H}_{2}}{{S}_{2}}{{O}_{8}}\]is    [MP PET 2002]

    A)                 + 2         

    B)                 + 4

    C)                 + 6         

    D)                 + 7

    Correct Answer: C

    Solution :

           The chemical structure of \[{{H}_{2}}{{S}_{2}}{{O}_{8}}\] is as follows:-            \[H-O-\underset{O}{\overset{O}{\mathop{\underset{||}{\overset{||}{\mathop{S}}}\,}}}\,-O-O-\underset{O}{\overset{O}{\mathop{\underset{||}{\overset{||}{\mathop{S}}}\,}}}\,-O-H\]            So the oxidation number of S should be :                                 \[\underset{(\text{for}\,\,H)}{\mathop{2\times (+1)}}\,+\underset{(\text{for}\,\,S)}{\mathop{2\times X}}\,+\underset{(\text{for}\,\,O)}{\mathop{6\times (-2)}}\,+\underset{(\text{for}\,\,O-O)}{\mathop{2\times (-1)}}\,=0\] or \[X=+6\].


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