JEE Main & Advanced Chemistry Electrochemistry / विद्युत् रसायन Question Bank Topic Test - Electrochemistry

  • question_answer
    The standard electrode potential for the following reaction is + 1.33 V. What is the potential at pH = 2? \[C{{r}_{2}}O_{7}^{2-}(aq1M)+14{{H}^{\oplus }}(aq)+6{{e}^{-}}\]\[\xrightarrow{\,}\,2C{{r}^{3+}}(aq1M)+7{{H}_{2}}O(l)\]

    A) +1.82 V

    B) +1.99 V

    C) +1.608 V

    D) +1.054 V

    Correct Answer: D

    Solution :

    [d] \[{{E}_{C{{r}_{2}}O_{7}^{2-}/C{{r}^{3+}}}}\]
    \[=E_{C{{r}_{2}}O_{7}^{2-}/C{{r}^{3+}}}^{o}-\frac{0.0591}{6}\log \frac{{{[C{{r}^{3+}}]}^{2}}}{[C{{r}_{2}}O_{7}^{2-}]{{[{{H}^{+}}]}^{14}}}\]
    \[=1.33-\frac{0.0591}{6}\log \frac{1}{{{(0.01)}^{14}}}\]
    \[=1.0542\text{ }V\]


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