JEE Main & Advanced Chemistry Electrochemistry / विद्युत् रसायन Question Bank Topic Test - Electrochemistry

  • question_answer
    A cell diagram shown below contains one litre of Buffer solution \[HA(p{{K}_{a}}=8)\] and NaA in both compartment. What is the cell emf?

    A) 0.81 V

    B) 0.071 V 

    C) 0.0591 V

    D) 1.182 V

    Correct Answer: C

    Solution :

    [c] \[{{E}_{cell}}=\frac{0.0591}{1}\log \frac{{{[{{H}^{+}}]}_{RHS}}}{{{[{{H}^{+}}]}_{LHS}}}\]
    \[{{E}_{cell}}=0.0591[p{{H}_{LHS}}-p{{H}_{RHS}}]\]
    \[p{{H}_{LHS}}p{{K}_{a}}+\log \frac{[{{A}^{-}}]}{[HA]}\]
    \[=8+\log \frac{1}{0.1}=9\]       \[p{{H}_{RHS}}=8\]
    \[{{E}_{cell}}=0.0591(9-8)=0.0591V\]


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