JEE Main & Advanced Chemistry Electrochemistry / विद्युत् रसायन Question Bank Topic Test - Electrochemistry

  • question_answer
    Salts of A (atomic weight: 7), B (atomic weight: 27), and C (atomic weight: 48) were electrolyzed under identical condition using the same quantity of electricity. It was found that when 2.1 got A was deposited, the weights of B and C deposited were 2.7 and 7.2 g, respectively. The valencies of A, B and C, respectively are:

    A) 3, 1 and 2

    B) 1, 3 and 2   

    C) 3, 1 and 3

    D) 2, 3 and 2

    Correct Answer: B

    Solution :

    [b] Eq. of A = Eq. of B = Eq. of C
    \[\frac{2.1}{7/{{n}_{1}}}=\frac{2.7}{27/{{n}_{2}}}=\frac{7.2}{48/{{n}_{3}}}\]
    \[0.3{{n}_{1}}=0.1{{n}_{2}}=0.15{{n}_{3}}\]
    \[\therefore \]      \[{{n}_{1}}=\frac{{{n}_{2}}}{3}=\frac{{{n}_{3}}}{2}=\left( {{n}_{1}},{{n}_{2}},{{n}_{3}} \right)\] are integers.


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