JEE Main & Advanced Chemistry Analytical Chemistry Question Bank Volumetric Analysis

  • question_answer
    Acidic solution of \[{{S}_{2}}O_{3}^{2-}\] is converted to ....... in presence of \[{{I}_{2}}\] [Orissa JEE 2005]

    A) \[{{S}_{4}}O_{6}^{2-}+{{I}^{-}}\]

    B) \[SO_{4}^{2-}+{{I}^{-}}\]

    C) \[S{{O}_{3}}+{{I}^{-}}\]

    D) \[{{S}_{4}}O_{6}^{2-}+I_{3}^{-}\]

    Correct Answer: A

    Solution :

    \[{{I}_{2}}+N{{a}_{2}}{{S}_{2}}{{O}_{3}}\to 2NaI+N{{a}_{2}}{{S}_{4}}{{O}_{6}}\] \[{{I}_{2}}+{{S}_{2}}O_{3}^{2-}\to 2{{I}^{-}}+{{S}_{4}}O_{6}^{2-}\]


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