12th Class Chemistry Sample Paper Chemistry Sample Test Paper-4

  • question_answer
      (a) The chemistry of corrosion of iron is essentially an electrochemical phenomenon. Explain the reactions occurring during the corrosion of iron in the atmosphere. (b) Express the relation between conductivity and molar conductivity of a solution held in a cell.                                                        

    Answer:

      (a) Corrosion is the oxidative deterioration of a metal, such as conversion of iron to rust the tarnishing of silver (due to the formation of ), development of a green coating on copper and bronze. Corrosion is basically an electrochemical phenomenon. A metal is oxidised by loss of electrons to oxygen, and forms metal oxides. Corrosion of iron (rusting) occurs in presence of water and oxygen (air). At one spot of an iron object, oxidation occurs and this is thus the anode. Anode   Electrons from the anode move through the metal and go another spot on the metal and reduce in presence of ions.( gets dissolved in water forming and which releases  ions, ). This spot where reduction takes place is the cathode. Cathode Net                            [1] ions move through water on the surface of the iron object. If water present in saline, it will help more in carrying the current in the electrochemical cell formed. Fe2+ ions are further oxidised by atomospheric O2 to Fe3+ (as ) and comes out as rust in the form of a hydrated iron (III) oxide represented as ions produced in this reaction help in further rusting.                     [1] (b) Molar conductance at concentrationConductivity (specific conductance)  Then, is practically expressed in the unit of (conductivity) = conductance x cell constant.          [1]


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