Answer:
(a)
(b)
Secondary
amine
Tertiary
amine
Secondary
amine gives insoluble substance with benzene sulphonyl chloride which remains
un- effected on addition of acid
Tertiary
amine do not react with benzene sulphonyl chloride and remains insoluble in
alkali and can be dissolved in acid
Primary
amine
Aromatic
amine
It gives
carbyl amine test.
Primary
amine gives foul smell with chloroform and alkali.
Aromatic
amines do not give carbyl amine test.
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