12th Class Chemistry Sample Paper Chemistry Sample Test Paper-9

  • question_answer
      Account for the following : (a) Phenol has a smaller dipole moment than methanol.                                                                                               1 (b) Unlike phenols, alcohols are easily protonated.                                                                                                          1 (c) Alcohols act as weak bases.                                                                                                                                                  1

    Answer:

      (a) Phenol has smaller dipole moment than methanol due to electron withdrawing effect of phenyl group. As a result the in phenol is less polar.                                                                                                                    On the other hand, in methanol the methyl group is electron releasing effect and hence group is more polar and dipole moment of phenol is higher than methanol.                                                                                                   (b) Phenyl group is electron withdrawing in nature. Therefore electron density on oxygen of group decreases. So, it is easily protonated. In case of alcohols, the alkyl group is effect group which increases the density on oxygen atom. Therefore it is not easily protonated.                                                                                                                                           1 (c) Alcohols acts as weak bases due to presence of lone pair on oxygen atom.                                                                                                              1


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