JEE Main & Advanced Sample Paper JEE Main - Mock Test - 25

  • question_answer
    A compound of formula \[{{A}_{2}}{{B}_{3}}\] has the hcp lattice. Which atom forms the hcp lattice and what fraction of tetrahedral voids is occupied by the other atoms:

    A) hcp lattice - A, \[\frac{2}{3}\] Tetrahedral voids - B

    B)        hcp lattice - A, \[\frac{1}{3}\] Tetrahedral voids - B

    C)        hcp lattice - B, \[\frac{2}{3}\] Tetrahedral voids - A

    D)        hcp lattice - B, \[\frac{1}{3}\] Tetrahedral voids - A

    Correct Answer: D

    Solution :

    Here, \[{{\operatorname{A}}_{2}}{{B}_{3}}\] can also be written as \[{{\operatorname{A}}_{4}}{{B}_{6}}\]. Since, hcp has six atoms, so ?B? forms hcp lattice and ?A? is present in void. \[\operatorname{Total} tetrahedral voids = 12\] \[\therefore \] Fraction of tetrahedral voids occupied by \[A=4/12=\frac{1}{3}\]


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