JEE Main & Advanced Sample Paper JEE Main - Mock Test - 43

  • question_answer
    Consider the following compounds I to IV with respect to their Su2 reactivity with a given nucleophile \[\underset{I}{\mathop{C{{H}_{3}}C{{H}_{2}}Br}}\,\]                     \[\underset{II}{\mathop{C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}Br}}\,\] \[\underset{III}{\mathop{{{\left( C{{H}_{3}} \right)}_{2}}CHC{{H}_{2}}Br}}\,\]    \[\underset{IV}{\mathop{{{\left( C{{H}_{3}} \right)}_{3}}CC{{H}_{2}}Br}}\,\] The correct order of decreasing reactivity is -

    A) IV>III>II>I  

    B)        I>IV>III>II

    C) IV>I>II>III  

    D)        I>II>III>IV

    Correct Answer: D

    Solution :

    [d] Rate of \[S{{N}_{2}}\] \[reaction\,\propto \frac{1}{steric\,hindrance}\] (ii) > (in) > (iv)


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