JEE Main & Advanced Sample Paper JEE Main - Mock Test - 4

  • question_answer
    Sodium extract of which of the following compounds does not form blood red ppt. with aqueous \[FeC{{l}_{3}}\]?

    A) \[N{{H}_{2}}N{{H}_{2}}\]      

    B) \[N{{H}_{2}}-\underset{\begin{smallmatrix}  || \\  O \end{smallmatrix}}{\mathop{C}}\,-N{{H}_{2}}\]

    C) \[C{{H}_{3}}-\underset{\begin{smallmatrix}  | \\  SH \end{smallmatrix}}{\mathop{C}}\,-C{{H}_{2}}N{{H}_{2}}\]

    D) Both [a] and [b]

    Correct Answer: D

    Solution :

    [d]: Compound with N, S and carbon will form NaSCN to give red ppt. \[Na+C+N+S\xrightarrow[{}]{{}}NaSCN\] \[F{{e}^{3+}}+SC{{N}^{-}}\xrightarrow[{}]{{}}\underset{(Blood\,red)}{\mathop{{{[Fe(SCN)]}^{2+}}}}\,\]


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