JEE Main & Advanced Sample Paper JEE Main Sample Paper-29

  • question_answer
    Arrange the following molecules in decreasing order of basic character
    A.\[Ce{{(OH)}_{3}}\]
    B.\[Dy{{(OH)}_{3}}\]
    C \[\Pr {{(OH)}_{3}}\]
    D.\[Lu{{(OH)}_{3}}\]

    A) A > B > C > D     

    B) A > C > B > D

    C) D > C > B > A     

    D) C > A > B > D

    Correct Answer: B

    Solution :

    Charge density increases from \[=(\ell n\,a)\,\underset{x\to 0}{\mathop{Lim}}\,\,\frac{1}{\frac{(1-\cos x)}{x}+\frac{x}{x}}\,=\ell n\,a\] to \[=(\ell n\,a)\,\underset{x\to 0}{\mathop{Lim}}\,\,\frac{x-1}{\ell n(x)}\] \[x=1+h\] Ce-0 bond becomes stronger hence becomes weaker in basic nature.


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