JEE Main & Advanced Sample Paper JEE Main Sample Paper-47

  • question_answer
    Aspartame on hydrolysis forms two amino acids
    I.\[{{H}_{2}}N\cdot \underset{\begin{smallmatrix}  | \\  C{{H}_{2}} \end{smallmatrix}}{\mathop{C}}\,H\cdot COOH\]
    II. \[{{H}_{2}}N\cdot \overset{\begin{smallmatrix}  C{{H}_{2}}{{C}_{6}}{{H}_{5}} \\  | \end{smallmatrix}}{\mathop{C}}\,H\cdot COOH\]
    III. \[{{H}_{2}}N\cdot \underset{\begin{smallmatrix}  | \\  C{{H}_{2}}COOH \end{smallmatrix}}{\mathop{C}}\,H\cdot CON{{H}_{2}}\]
    IV.\[{{H}_{2}}N\cdot CHCOHN\cdot \overset{\begin{smallmatrix}  C{{H}_{2}}{{C}_{6}}{{H}_{5}} \\  | \end{smallmatrix}}{\mathop{C}}\,H\cdot COOH\]
    The structures of the amino acids are represented by

    A)  I, II                             

    B)  III, IV                

    C)  I, III                            

    D)  II, IV

    Correct Answer: A

    Solution :

     \[{{H}_{2}}N\underset{\begin{smallmatrix}  | \\  C{{H}_{2}}COOH \end{smallmatrix}}{\mathop{C}}\,HCONH\cdot \overset{\begin{smallmatrix}  C{{H}_{2}}{{C}_{6}}{{H}_{5}} \\  | \end{smallmatrix}}{\mathop{C}}\,H\cdot COOC{{H}_{3}}\,\xrightarrow{HOH}\]\[{{H}_{2}}N\cdot \underset{\begin{smallmatrix}  | \\  C{{H}_{2}}COOH \end{smallmatrix}}{\mathop{C}}\,H\cdot COOH+N{{H}_{2}}\cdot \overset{\begin{smallmatrix}  C{{H}_{2}}{{C}_{6}}{{H}_{5}} \\  | \end{smallmatrix}}{\mathop{C}}\,H\cdot COOH\]


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