KVPY Sample Paper KVPY Stream-SX Model Paper-12

  • question_answer
    Which of the following is true statement about the reaction?

    A) o- isomer is major if PhONa is used

    B) p-isomer is major if PhOK is used

    C) Product formed is further used for preparation of drug Asprin

    D) All of these

    Correct Answer: D

    Solution :

    \[{{K}^{\oplus }}\]cation is larger and is likely to be less effective in chelation. So that attack on the p-position. When NaOH is used then dianion formed in Kolbe-Schmidt reaction is stabilize by \[N{{a}^{+}}\]which is not possible for \[{{K}^{+}}\] ion.


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