KVPY Sample Paper KVPY Stream-SX Model Paper-18

  • question_answer
    Copper metal on treatment with dilute \[HN{{O}_{3}}\] produces a gas (X). X, when passed through acidic solution of stannous chloride, a nitrogen containing (Y) is obtained. Which on reaction with nitrous acid produces a gas (Z) is

    A) \[NO\]  

    B) \[{{N}_{2}}\]

    C) \[N{{O}_{2}}\]

    D) \[{{N}_{2}}O\]

    Correct Answer: D

    Solution :

    Cu produces NO (X) gas when treated with dil.\[HN{{O}_{3}}.\] This gas is reduced to \[N{{H}_{2}}OH\cdot HCI\,(Y)\] by \[SnC{{l}_{2}}/HCl\] and then oxidised by \[HN{{O}_{2}}\] give \[{{N}_{2}}O\,(Z).\]The reaction is as follows:
    \[Cu+Dil.HN{{O}_{3}}\xrightarrow{{}}\underset{(X)}{\mathop{NO}}\,\xrightarrow{SnC{{l}_{2}}/HCl}\]\[N{{H}_{2}}\underset{(Y)}{\mathop{OH}}\,\cdot HCl\xrightarrow{HN{{O}_{2}}}\underset{(Z)}{\mathop{{{N}_{2}}O}}\,\]


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