KVPY Sample Paper KVPY Stream-SX Model Paper-3

  • question_answer
    Which of the following statement(s) is/are false -

    A) p-chloro phenol is more acidic than p-flouro phenol

    B) \[-\overset{\oplus }{\mathop{N}}\,M{{e}_{3}}\] is stronger -I group than \[-\overset{\oplus }{\mathop{N}}\,{{H}_{3}}\]

    C) Acidity order: o-nitrobenzoic acid > p-nitrobenzoic acid > m-nitrobenzoic acid

    D) Acidity order:\[{{H}_{3}}C-COOH<{{H}_{3}}Si-\overset{O}{\mathop{\overset{\parallel }{\mathop{C}}\,}}\,-OH\]

    Correct Answer: D

    Solution :

    [D] [a] Overall withdrawing power of Cl is greater than F in conjugation. [c] [d] \[Si{{H}_{3}}\]is better +I than \[-\,C{{H}_{3}}\]


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