A) 2-chloropropane
B) allyl chloride
C) n-propyl chloride
D) isopropyl chloride
Correct Answer: A
Solution :
[a] Peroxide effect is observed only in case of \[HBr\]. Therefore, addition of \[HCl\] to propene even in the presence of berizoyl peroxide occurs according to Markownikoffs rule. \[C{{H}_{3}}\underset{\text{Porpene}}{\mathop{CH=}}\,C{{H}_{2}}\xrightarrow[{{({{C}_{6}}{{H}_{5}}COO)}_{2}}]{HCl}C{{H}_{3}}\underset{2-\text{chloropropane}}{\mathop{-\overset{\begin{smallmatrix} Cl \\ | \end{smallmatrix}}{\mathop{CH}}\,}}\,-C{{H}_{3}}\]
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