KVPY Sample Paper KVPY Stream-SX Model Paper-9

  • question_answer
    Element A bums in nitrogen to give an ionic compound B. Compound B reacts with water to give C and D. A solution of C becomes 'milky' on bubbling carbon dioxide. Identify A, B, C and D.

    A) \[S,\text{ }{{S}_{3}}{{N}_{2}},\text{ }S{{O}_{2}}\]

    B) \[C,\text{ }{{C}_{2}}{{N}_{2}},\text{ }N{{H}_{3}}\]

    C) \[Fe,\text{ }FeO,\text{ }Fe{{\left( OH \right)}_{2}}\]

    D) \[Ca,\text{ }C{{a}_{3}}{{N}_{2}},\text{ }Ca{{\left( OH \right)}_{2}}\]

    Correct Answer: D

    Solution :

    \[\underset{Metal\,\,(A)}{\mathop{3Ca}}\,+{{N}_{2}}\to \underset{(B)calcium\,\,nitrate}{\mathop{C{{a}_{3}}{{N}_{2}}}}\,\]    
    (The case of formation of nitrides decreases from Be \[\to \] Ba)                        
    \[\underset{(B)}{\mathop{C{{a}_{3}}{{N}_{2}}}}\,+6{{H}_{2}}O\to \underset{(C)}{\mathop{3\,Ca\,\,{{(OH)}_{2}}}}\,+\underset{(D)}{\mathop{2\,N{{H}_{3}}}}\,\]
    cal. hydroxide               
    \[Ca\,\,{{(OH)}_{2}}+\underset{Milkiness}{\mathop{C{{O}_{2}}\to CaC{{O}_{3}}}}\,\downarrow +{{H}_{2}}O\]


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