NEET Sample Paper NEET Sample Test Paper-11

  • question_answer
    A steady current of 1.5 A flows through a copper volammeter for 10 min. If the electrochemical equivalent of copper is\[30\times {{10}^{-5}}g{{C}^{-1}},\] the mass of copper deposited on the electrode will be

    A)  0.40 g                         

    B)  0.50 g

    C)  0.67 g                         

    D)  0.27 g

    Correct Answer: D

    Solution :

     Apply first law of electrolysis during deposition of charge on an electrode through electrolysis. If\[m\]is the mass of a substance deposited or  liberated at an electrode during electrolysis, when a charge q passes through electrolyte, then according to Faraday's first law of electrolysis,                          \[m\propto q\] or                      \[m=zq\] where z is a constant of proportionality and is called electrochemical equivalent (ECE) of the  substance. If an electric current/flows through the electrolyte, then q=It M= zit Here, \[i=1.5\,A,t=10\,\min =10\times 60\,s\] \[z=30\times {{10}^{-5}}\,g{{C}^{-1}}\] Hence, mass of copper deposited on the electrode \[m=30\times {{10}^{-5}}\times 1.5\times 10\times 60\] \[27\times {{10}^{-2}}=0.27g\]


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