NEET Sample Paper NEET Sample Test Paper-27

  • question_answer
    For the reversible system \[{{X}_{(g)}}{{Y}_{(g)}}+{{Z}_{(g)}}\] a quantity of X was heated at constant pressure P at a certain temperature. The equilibrium partial pressure of X was found to be \[\frac{P}{7}\]. What is the vlaue of \[{{K}_{P}}\] at given temperature?

    A)  \[\frac{6P}{7}\]                    

    B)  \[\frac{9P}{7}\]

    C)  \[\frac{36P}{7}\]                  

    D)  \[6P\]

    Correct Answer: B

    Solution :

    \[\begin{matrix}    X  \\    a  \\    a-x  \\ \end{matrix}\begin{matrix}      \\    {}  \\    {}  \\ \end{matrix}\begin{matrix}    Y  \\    a  \\    x  \\ \end{matrix}\begin{matrix}    +  \\    {}  \\    {}  \\ \end{matrix}\begin{matrix}    Z  \\    a  \\    x  \\ \end{matrix}\] \[P_{x}^{'}=P\frac{(a-x)}{(a+x)}=\frac{P}{7}\] \[7a-7a=a+x\] \[6a=8x\] \[x=\frac{6a}{8}=\frac{3a}{4}\] \[{{K}_{P}}=\frac{{{x}^{2}}}{(a-x)}\frac{[P]}{\left[ a+x] \right]}\] \[=\frac{{{\left( \frac{3a}{4} \right)}^{2}}[P]}{\left( a-\frac{3a}{4} \right)\left( a+\frac{3a}{4} \right)}\] \[=\frac{9{{a}^{2}}\times 4\times 4\times P}{16\times a\times 7a}\] \[{{K}_{P}}=\frac{9P}{7}\]


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