NEET Sample Paper NEET Sample Test Paper-27

  • question_answer
    The enthalpy of neutralization of \[NaOH\] with acetic acid is \[55\text{ }kJ\] and with \[HCl\] is\[57.1\text{ }kJ\]. This happens because

    A)  some heat is required for complete ionisation of acetic acid

    B)  acetic acid is an organic acid

    C)  acetic acid is less soluble in water

    D)  acetic acid is a weak acid and required lesser alkali

    Correct Answer: A

    Solution :

    The enthalpy of neutralization of weak acid with strong base is always lesser than the strong acid with strong base. Therefore, the enthalpy of neutralisation of \[NaOH\] with \[C{{H}_{3}}COOH\] is \[55\text{ }KJ\]and with \[HCl\] is\[57.1\text{ }KJ\]. This is due to that weak acid is not completely dissociated. Hence, some of heat is utilised for complete ionisation of weak acid. i.e. \[C{{H}_{3}}COOH\].


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