NEET Sample Paper NEET Sample Test Paper-30

  • question_answer
    The Van't Hoff factor for \[0.1M\] \[Ba{{(N{{O}_{3}})}_{2}}\] solution is\[2.74\]. The degree of dissociation is:

    A)  \[91.3%\]                   

    B)  \[87%\]

    C)  \[100%\]                    

    D)  \[74%\]

    Correct Answer: B

    Solution :

    \[\begin{matrix}    {}  \\    At\,t=0  \\    At\text{ }eqm  \\ \end{matrix}\,\,\,\,\begin{matrix}    Ba{{\left( N{{O}_{3}} \right)}_{2}}  \\    0.1\,M  \\    (0.1-x)M  \\ \end{matrix}\,\,\begin{matrix}      \\    {}  \\    {}  \\ \end{matrix}\begin{matrix}    B{{a}^{2+}}  \\    0  \\    xM  \\ \end{matrix}\,\,\begin{matrix}    +  \\    {}  \\    {}  \\ \end{matrix}\,\,\,\begin{matrix}    2NO_{3}^{-}  \\    0  \\    2x\,M  \\ \end{matrix}\]             \[i=\frac{(0.1-x)+x+2x}{0.1}\]             \[2.74=\frac{0.1+2x}{0.1}\]             \[0.1+2x=0.27\,4\]           \[2x=0.274-0.1=0.174\]           \[x=\frac{0.174}{2}=0.087\] \[\therefore \]degree of dissociation                         \[=\frac{0.087}{0.1}\times 100=87%\]


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