A) \[N{{H}_{3}}>C{{H}_{3}}N{{H}_{2}}>{{C}_{2}}{{H}_{5}}N{{H}_{2}}>{{C}_{6}}{{H}_{5}}N{{H}_{2}}\]
B) \[{{C}_{2}}{{H}_{6}}N{{H}_{2}}>C{{H}_{3}}N{{H}_{2}}>N{{H}_{3}}>{{C}_{6}}{{H}_{5}}N{{H}_{2}}\]
C) \[{{C}_{6}}{{H}_{5}}N{{H}_{2}}>{{C}_{2}}{{H}_{5}}N{{H}_{2}}>C{{H}_{3}}N{{H}_{2}}>N{{H}_{3}}\]
D) \[C{{H}_{3}}N{{H}_{2}}>{{C}_{2}}{{H}_{5}}N{{H}_{2}}>{{C}_{6}}{{H}_{6}}N{{H}_{2}}>N{{H}_{3}}\]
Correct Answer: B
Solution :
Due to presence of \[+I\] effect of alkyl group aliphatic amines are stronger bases than \[N{{H}_{3}}\]while aromatic amines are weaker bases than \[N{{H}_{3}}\] due to \[-I\] effect of phenyl group. Hence, the order of basicity is as: \[{{C}_{2}}{{H}_{5}}N{{H}_{2}}>C{{H}_{3}}N{{H}_{2}}>N{{H}_{3}}>{{C}_{6}}{{H}_{5}}N{{H}_{2}}\]
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