JEE Main & Advanced Chemistry Chemical Kinetics / रासायनिक बलगतिकी Sample Paper Topic Test - Chemical Kinetics

  • question_answer
    The forward rate constant for the reversible gaseous reaction \[{{C}_{2}}{{H}_{6}}2C{{H}_{3}}\] is\[3.14\times {{10}^{+2}}{{s}^{-1}}\] at 200 K. What is the rate constant for the backward reaction at this temperature, if \[{{10}^{-5}}\] moles of \[C{{H}_{3}}\] and 100 mol of \[{{C}_{2}}{{H}_{6}}\] are present in 10 L vessel at equilibrium?

    A) \[1.57\times {{10}^{14}}Lmo{{l}^{-1}}{{s}^{-1}}\]

    B) \[3.14\times {{10}^{15}}Lmo{{l}^{-1}}{{s}^{-1}}\]

    C) \[1.57\times {{10}^{7}}Lmo{{l}^{-1}}{{s}^{-1}}\]

    D) \[3.14\times {{10}^{10}}Lmo{{l}^{-1}}{{s}^{-1}}\]

    Correct Answer: B

    Solution :

    \[{{k}_{eq}}=\frac{{{k}_{1}}}{{{k}_{b}}}=\frac{{{[C{{H}_{3}}]}^{2}}}{[{{C}_{2}}{{H}_{6}}]}\]
    \[[C{{H}_{3}}]=\frac{{{10}^{-5}}}{10}mol{{L}^{-1}}={{10}^{-6}}mol{{L}^{-1}}\]
    \[[{{C}_{2}}{{H}_{6}}]=\frac{100}{10}=10mol{{L}^{-1}}=10M\]
    \[{{k}_{eq}}=\frac{{{k}_{f}}}{{{k}_{b}}}\]
    \[\frac{{{[{{10}^{-6}}]}^{2}}}{10}=\frac{3.14\times {{10}^{2}}{{s}^{-1}}}{{{k}_{b}}}\]
    \[{{k}_{b}}=3.14\times {{10}^{3+12}}Lmo{{l}^{-1}}{{s}^{-1}}\]
    \[=3.14\times {{10}^{15}}Lmo{{l}^{-1}}{{s}^{-1}}\]


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