JEE Main & Advanced Chemistry Structure of Atom / परमाणु संरचना Sample Paper Topic Test - Structure of Atom

  • question_answer
    Let \[{{v}_{1}}\] be the frequency of the series limit of the Lyman series, \[{{v}_{2}}\] be the frequency of the first line of the Lyman series, and \[{{v}_{3}}\] be the frequency of the series limit of the Balmer series, then

    A) \[{{v}_{3}}=\frac{1}{2}({{v}_{1}}-{{v}_{3}})\]

    B) \[{{v}_{2}}-{{v}_{1}}={{v}_{3}}\]

    C) \[{{v}_{1}}-{{v}_{2}}={{v}_{3}}\]

    D) \[{{v}_{1}}+{{v}_{2}}={{v}_{3}}\]

    Correct Answer: C

    Solution :

    [c]  \[{{v}_{1}}=Rc\,{{Z}^{2}}\left( \frac{1}{n_{1}^{2}}-\frac{1}{n_{2}^{2}} \right)\]
    \[{{v}_{1}}=Rc\,{{Z}^{2}}\left( \frac{1}{{{1}^{2}}}-\frac{1}{{{\infty }^{2}}} \right)=Rc\,{{Z}^{2}}\]
    \[{{v}_{2}}=Rc\,{{Z}^{2}}\left( \frac{1}{{{1}^{2}}}-\frac{1}{{{2}^{2}}} \right)=\frac{3\,Rc\,{{Z}^{2}}}{4}\]
    \[{{v}_{3}}=Rc\,{{Z}^{2}}\left( \frac{1}{{{2}^{2}}}-\frac{1}{{{\infty }^{2}}} \right)=\frac{2\,Rc\,{{Z}^{2}}}{4}\]
    \[\therefore \]      \[{{v}_{1}}-{{v}_{2}}={{v}_{3}}\]


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