JEE Main & Advanced AIEEE Paper (Held On 11 May 2011)

  • question_answer
    Resistance of 0.2 M solution of an electrolyte is \[50\Omega .\]The specific conductance of the solution is \[1.3S\,{{m}^{-1}}.\]If resistance of the 0.4 M solution of the same electrolyte is \[260\Omega ,\]its molar conductivity is :     AIEEE  Solved  Paper (Held On 11 May  2011)

    A) \[6.25\times {{10}^{-4}}S{{m}^{2}}\,mo{{l}^{-1}}\]

    B) \[625\times {{10}^{-4}}S\,{{m}^{2}}\,mo{{l}^{-1}}\]

    C) \[62.5\,S\,{{m}^{2}}\,mo{{l}^{-1}}\]

    D) \[6250\,S\,{{m}^{2}}\,mo{{l}^{-1}}\]

    Correct Answer: A

    Solution :

                                    \[k=\frac{1}{R}\times \frac{\ell }{A}\]                 \[1.3=\frac{1}{50}\times \frac{\ell }{A}\]                 \[\frac{\ell }{A}=65\,{{m}^{-1}}\] \[{{\Lambda }_{m}}=\frac{K}{100\times molarity}(\frac{K}{1000\times molarity})\] \[=\frac{\left( \frac{1}{2604}\times 64 \right)}{1000\times 0.40}=6.25\times {{10}^{-4}}=\frac{1}{4\times 0.4\times 1000}=\frac{1}{1600}=6.25\times {{10}^{-4}}S\,{{m}^{2}}mo{{l}^{-1}}\]


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