JEE Main & Advanced AIEEE Solved Paper-2002

  • question_answer
    At what temperature is the \[rms\] velocity of a hydrogen molecule equal to that of an oxygen molecule at \[{{47}^{o}}C\]?   AIEEE  Solved  Paper-2002

    A) 80 K                                          

    B) -73 K                        

    C) 3 K                            

    D)           20 K

    Correct Answer: D

    Solution :

    The rms velocity of the molecule of a gas of molecular weight M at kelvin temperature T is given by               \[{{C}_{rms}}=\sqrt{\left( \frac{3RT}{M} \right)}\]              Let \[{{M}_{O}}\] and \[{{M}_{H}}\] be molecular weights of oxygen and hydrogen and \[{{T}_{O}}\] and \[{{T}_{H}}\] the corresponding kelvin temperatures at which \[{{C}_{rms}}\] is same for both gases.              i.e.,            \[{{C}_{rms(O)}}={{C}_{rms(H)}}\]                 \[\sqrt{\left( \frac{3R{{T}_{O}}}{{{M}_{O}}} \right)}=\sqrt{\left( \frac{3R{{T}_{H}}}{{{M}_{H}}} \right)}\]              Hence,     \[\frac{{{T}_{O}}}{{{M}_{O}}}=\frac{{{T}_{H}}}{{{M}_{H}}}\]              Given,      \[{{T}_{O}}=273+47=320\,K\]                                 \[{{M}_{O}}\,=32,\,\,{{M}_{H}}=2\]    \[\therefore \]  \[{{T}_{H}}=\frac{2}{32}\times 320=20\,K\]


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