A) \[[Cu{{(N{{H}_{3}})}_{4}}][Pt\text{ }C{{l}_{4}}]\]and \[[Pt{{(N{{H}_{3}})}_{4}}][CuC{{l}_{4}}]\]
B) \[[Pd{{(P\text{ }P{{h}_{3}})}_{2}}{{(NCS)}_{2}}]\]and \[[Pd{{(P\text{ }P{{h}_{3}})}_{2}}{{(SCN)}_{2}}]\]
C) \[[CO{{(N{{H}_{3}})}_{5}}\text{ }N{{O}_{3}}]S{{O}_{4}}\] and \[[CO{{(N{{H}_{3}})}_{5}}S{{O}_{4}}]N{{O}_{3}}\]
D) \[[PtC{{l}_{2}}{{(N{{H}_{3}})}_{4}}]B{{r}_{2}}\]and \[[Pt\text{ }B{{r}_{2}}{{(N{{H}_{3}})}_{4}}]C{{l}_{2}}\]
Correct Answer: B
Solution :
Linkage isomerism is shown by ambidient ligand like NCS and SCN \[\therefore \]\[[Pd(P\text{ }P{{h}_{3}})(NC{{S}_{2}})]\]and\[[Pd{{(PP{{h}_{3}})}_{2}}{{(SCN)}_{2}}]\]
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