NEET AIPMT SOLVED PAPER SCREENING 2007

  • question_answer
                    In which of the following pairs, the two species are iso-structural?                                          

    A)                 \[S{{F}_{4}}\] and \[Xe{{F}_{4}}\]

    B)                 \[SO_{3}^{2-}\] and \[NO_{3}^{-}\]

    C)                 \[B{{F}_{3}}\] and \[N{{F}_{3}}\]

    D)                 \[BrO_{3}^{-}\] and \[Xe{{O}_{3}}\]

    Correct Answer: D

    Solution :

                     \[S{{F}_{4}}=\] irregular tetrahedron (\[s{{p}^{3}}d\], one lone pair) \[Xe{{F}_{4}}=\] square planar (\[s{{p}^{3}}{{d}^{2}},\] two lone pair)                 \[SO_{3}^{2-}\] = pyramidal (\[s{{p}^{3}}\] one lone pair)  \[NO_{3}^{-}\] = trigonal planar \[(s{{p}^{2}})\]                 \[B{{F}_{3}}\]= trigonal planar \[(s{{p}^{2}})\] \[N{{F}_{3}}=\] pyramidal \[(s{{p}^{3}})\]                 \[BrO_{3}^{-}\] = pyramidal (\[s{{p}^{3}}\], one lone pair) \[Xe{{O}_{3}}=\] pyramidal (\[s{{p}^{3}},\] one lone pair)


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