NEET AIPMT SOLVED PAPER SCREENING 2008

  • question_answer
    On the basis of the following \[{{E}^{\text{o}}}\] values, the strongest oxidising agent is \[{{[Fe{{(CN)}_{6}}]}^{4-}}\to {{[Fe{{(CN)}_{6}}]}^{3-}}]+{{e}^{-}};\] \[{{E}^{o}}=-0.35V\] \[F{{e}^{2+}}\to F{{e}^{3+}}+{{e}^{-}};{{E}^{o}}=-0.77V\]

    A) \[{{[Fe{{(CN)}_{6}}]}^{4-}}\]      

    B)        \[F{{e}^{2+}}\]

    C) \[F{{e}^{3+}}\] 

    D) \[{{[Fe{{(CN)}_{6}}]}^{3-}}\]

    Correct Answer: C

    Solution :

                                    Key Idea: Oxidised form \[+n{{e}^{-}}\to \]Reduced form The substances which have' lower reduction potential are stronger reducing agent while the substances which have higher reduction potential are stronger oxidising agent. \[{{[Fe{{(CN)}_{6}}]}^{3-}}+{{e}^{-}}\to {{[Fe{{(CN)}_{6}}]}^{4-}};\]\[{{E}^{o}}=0.35V\] \[F{{e}^{3+}}+{{e}^{-}}\to F{{e}^{2+}};\]\[{{E}^{o}}=0.77V\] The reduction potential of \[F{{e}^{3+}}/F{{e}^{2+}}\] is higher, hence \[F{{e}^{3+}}\]is strongest oxidising agent.


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