NEET AIPMT SOLVED PAPER SCREENING 2008

  • question_answer
    How many stereoisomers does this molecule have?\[C{{H}_{3}}CH=CHC{{H}_{2}}\overset{*}{\mathop{C}}\,HBrC{{H}_{3}}\]

    A)

    B)                                        6                                             

    C) 8                             

    D)        2

    Correct Answer: A

    Solution :

    Key Idea: (i) Number of optical isomers \[={{2}^{n}}\]where, n = number of dissimilar asymmetric carbon atoms. (ii) Number of geometrical isomers \[={{2}^{n}}\] where, n = number of double bond only when the two ends of the chain are different \[C{{H}_{3}}CH=CH-C{{H}_{2}}-\underset{\begin{smallmatrix}  | \\  Br \end{smallmatrix}}{\overset{*}{\mathop{C}}}\,H-C{{H}_{3}}\] Here, number of optical isomers \[={{2}^{1}}=2\] Number of geometrical isomers \[={{2}^{1}}=2\] Hence, number of stereoisomers = 2 + 2 = 4


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