AMU Medical AMU Solved Paper-2013

  • question_answer
    The product obtained in the following reaction is\[C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}-\overset{\begin{smallmatrix}  O \\  || \end{smallmatrix}}{\mathop{C}}\,-N{{H}_{2}}\xrightarrow[\Delta ]{{{P}_{2}}{{O}_{5}}}?\]

    A)  \[C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}COOH\]

    B)  \[C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}-CN\]

    C)  \[C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}-\overset{\begin{smallmatrix}  OH \\  | \end{smallmatrix}}{\mathop{C}}\,-NH\]

    D)  None of the above

    Correct Answer: B

    Solution :

                    \[C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}-\overset{\begin{smallmatrix}  O \\  || \end{smallmatrix}}{\mathop{C}}\,-N{{H}_{2}}\xrightarrow[\Delta ]{{{P}_{2}}{{O}_{5}}}\]\[C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}CN\] Acid amides get dehydrated upon heating with phosphorus pentoxide \[({{P}_{2}}{{O}_{5}})\] to give cyanides.


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