A) primary amines
B) secondary amines
C) test amines
D) quaternary amines
Correct Answer: A
Solution :
Carbylamine test is given by only primary amines (both aliphatic and aromatic). Primary amines when warmed with chloroform and alcoholic KOH, give extremely bad smelling compounds called carbylamines or isocyanides. \[RN{{H}_{2}}+CHC{{l}_{3}}+3\,KOH(alc.)\]\[\xrightarrow[{}]{{}}RN\underset{\begin{smallmatrix} Alkyl \\ carbyla\min e \end{smallmatrix}}{\mathop{\underline{\underline{\xrightarrow[{}]{{}}}}}}\,C+3KCl+3{{H}_{2}}O\]
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