BCECE Engineering BCECE Engineering Solved Paper-2010

  • question_answer
    The order of decreasing stability of the carbanions is \[{{(C{{H}_{3}})}_{3}}\bar{C}(1),{{(C{{H}_{3}})}_{2}}\bar{C}H(2),C{{H}_{3}}\bar{C}{{H}_{2}}(3),\]\[{{C}_{6}}{{H}_{5}}\bar{C}{{H}_{2}}(4)\]

    A)  1 > 2 > 3 > 4                       

    B)  4 > 3 > 2 > 1       

    C)         1 > 2 > 4 > 3       

    D)         4 > 1 > 2 > 3

    Correct Answer: B

    Solution :

    The stability of the carbanion decreases with increase in number of alkyl groups. However, phenyl group stabilizes the carbanion due to resonance effect. \[\therefore \] The order of stability of given ions is as follows \[{{C}_{6}}{{H}_{5}}\bar{C}{{H}_{2}}>C{{H}_{3}}\bar{C}{{H}_{2}}>{{(C{{H}_{3}})}_{2}}\bar{C}H>{{(C{{H}_{3}})}_{3}}\bar{C}\]or                 \[4>3>2>1\]


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