BCECE Medical BCECE Medical Solved Papers-2001

  • question_answer
    The solubility of \[A{{g}_{2}}S\] is \[[{{K}_{sp}}=256\times {{10}^{-6}}]\] :

    A)  \[4\times {{10}^{-2}}\]

    B)  \[4\times {{10}^{-3}}\]

    C)  \[0.4\times {{10}^{-2}}\]

    D)  \[0.4\times {{10}^{-3}}\]

    Correct Answer: A

    Solution :

    Key Idea: Let solubility of \[A{{g}_{2}}S=x\,g/L\] \[\underset{Concentration}{\mathop{A{{g}_{2}}S}}\,\,\,\xrightarrow{{}}\underset{2x}{\mathop{A{{g}^{+}}}}\,+\underset{x}{\mathop{{{S}^{2}}}}\,\]                 \[{{K}_{sp}}={{[A{{g}^{+}}]}^{2}}[{{S}^{2-}}]\]                 \[={{(2x)}^{2}}(x)\]                 \[=4{{x}^{3}}\] Given,   \[{{K}_{sp}}=256\times {{10}^{-6}}\]                 \[\therefore \] \[256\times {{10}^{-6}}=4{{x}^{3}}\]                 or \[x=\sqrt[3]{\frac{25\times {{10}^{-6}}}{4}}\] \[=4\times {{10}^{-2}}\]


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